For all $n \geq 3$ the alternating group $A_{n}$ can be realized as the orientation-preserving symmetries of the regular $n$-simplex (triangle, tetrahedron, etc.). In this case the full symmetry group is $S_{n}$, and the relation between $A_{n}$ and $S_{n}$ can be seen geometrically. For instance, when $n = 3$, $A_{3}$ comprises the rotations through an angle of $2\pi/3$ of an equilateral triangle about its centroid, while $S_{3}$ includes additionally the reflections through the angle bisectors. One can relate these geometric descriptions to the usual descriptions in terms of permutations by looking at what the geometric transformations do to the triangle's vertices. The symmetries of the regular tetrahedron can be examined in a similarly explicit fashion.
The cardinality $60$ alternating group $A_{5}$ is also the group of rotational (orientation-preserving) symmetries of a regular icosahedron. (This example has the virtue of being visualizable in three-dimensional space. It has the defect of being peculiar to $n = 5$.)
Although somewhat complicated for beginning students, this can be written down explicitly in the following way that uses only introductory linear algebra. Take as the $12$ vertices of the isosahedron the cyclic permutations of $(\pm 1, \pm w, 0)$ where $w = (1 + \sqrt{5})/2$. The icosahedron is the convex hull of these $12$ points. $A_{5}$ is generated by the order $2$ map sending $x = (x_{1}, x_{2}, x_{3}) \to (-x_{1}, -x_{2}, x_{3})$, the order $3$ map sending $x = (x_{1}, x_{2}, x_{3}) \to (x_{2}, x_{3}, x_{1})$ (which is rotation by $2\pi/3$ about the axis $(1, 1, 1)$), and the order $5$ map given by rotating by $2\pi/5$ around the axis spanned by any one of the vertices. (Adding $x \to -x$ yields the cardinality $120$ full symmetry group of the icosahedron; note, however, that this is $A_{5}\times \mathbb{Z}_2$ and not the symmetric group $S_{5}$.) It is instructive for students to think about what is permuted by this action of $A_{5}$.
Comparing the two different geometric descriptions of $A_{5}$, as the rotational symmetries of an icosahedron and the rotational symmetries of a regular simplex, would be instructive (they are associated with different irreducible representations of $A_{5}$, of dimensions $3$ and $4$).