One can only see that this is true just as one saw what the symbols $1,2,3,\cdots$ meant. What's happening in this case is that we are seeing a ratio. Suppose we want $n/100$ of $Q.$ Then you may explain this to them as
Divide $Q$ into $100$ equal parts, and take $n$ of such parts of $100.$ That is, we're taking $n$ of something. But this simply means we add $n$ such things together, which means we are multiplying such things by $n.$
NB. The explanation above will be clearer if you've previously introduced positive integer multiplication as a short notation for iterated addition, and will make sense therefore only if $n$ is a positive integer. Using this convention more generally is just a matter of agreement, as with most other operations outside $\mathbf N.$ However, the explanation for $n\in\mathbf N$ should be a good motivation as to why this convention of thinking of 'of' as some type of multiplication (later when they learn about functions and the notation $f(x),$ they're going to have a nod of déjà vu!) is most useful, convenient, and agrees with the fact in $\mathbf N.$